======Copper Oxide and Zinc Displacement Reaction====== **Materials: **{{$demo.materials_description}}\\ **Difficulty: **{{$demo.difficulty_description}}\\ **Safety: **{{$demo.safety_description}}\\ \\ **Categories:** {{$demo.categories}} \\ **Alternative titles:** Zinc Reduces Copper Oxide ====Summary==== {{$demo.summary}} ====Procedure==== - Mix small amounts of powdered copper(II) oxide (black) and zinc powder in a heat-resistant container such as a crucible. - Place the container in a fume hood or well-ventilated area with a heat shield. - Use a flame to supply activation energy to one spot in the mixture. - Observe as the reaction spreads through the mixture, releasing bright light and intense heat. - Note color changes: copper oxide (black) turns into zinc oxide (yellow-hot, white when cool) and copper metal (red-brown, may glow). - Allow the reaction to cool completely. - To confirm copper, add dilute hydrochloric acid to dissolve zinc oxide and excess zinc, leaving copper metal behind. ====Links==== Reaction between zinc and copper(II) oxide - chemistry edb: {{youtube>9qfluTAIsPU?}}\\ Displacement reaction of zinc and copper(II) oxide - Andy's Chemistry: {{youtube>6_rReZhVcI8?}}\\ ====Variations==== * Try initiating with a magnesium strip fuse to make ignition safer. * Demonstrate alongside a classic aluminum-iron oxide thermite for comparison of energy release. ====Safety Precautions==== * Wear safety goggles, heat-resistant gloves, and a lab coat. * Perform behind a safety screen; the reaction is highly exothermic and may spatter molten material. * Handle zinc powder with care; it is flammable in fine form. * Do not look directly at the bright reaction for long periods to avoid eye strain. * Hydrochloric acid is corrosive; handle with care and neutralize spills promptly. * Allow crucible and products to cool fully before handling. ====Questions to Consider==== * What type of reaction is this? (A single displacement redox reaction) * Which element is oxidized and which is reduced? (Zinc is oxidized to Zn²⁺; copper is reduced to Cu metal) * Why does the reaction release so much heat? (The formation of zinc oxide is highly exothermic, driving the process) * How can you confirm that copper has been formed? (By dissolving zinc oxide and excess zinc with dilute hydrochloric acid, leaving copper behind) * How is this reaction similar to and different from a thermite reaction? (Both are highly exothermic metal-oxide reductions; this one produces copper instead of iron and can be done on a smaller scale)