======Halogen Displacement====== **Materials: **{{$demo.materials_description}}\\ **Difficulty: **{{$demo.difficulty_description}}\\ **Safety: **{{$demo.safety_description}}\\ \\ **Categories:** {{$demo.categories}} \\ **Alternative titles:** Halogen Reactivity Series ====Summary==== {{$demo.summary}} ====Procedure==== - Place a few drops of each potassium halide salt solution (KCl, KBr, KI) into separate wells on a spotting tile. - Add a few drops of chlorine water to each well and observe any changes. - Repeat the process using bromine water and iodine water, testing each halogen solution against all three halide salts. - Look for color changes, precipitate formation, or fading of color (distinguishing real reactions from dilution). - Test the pH of each well with universal indicator paper. - Compare results to determine which halogen has displaced another. ====Links==== Halogen Displacement Reactions - Royal Society of Chemistry: {{youtube>TMwpLNZJmQo?}}\\ Displacement of Halogens - Rugby School Chemistry: {{youtube>MC8kEpWMSkk?}}\\ 📄 Halogen Displacement - Practical Science: [[https://practical-science.com/2023/04/08/halogen-displacement/]]\\ ====Variations==== * Record the intensity of color changes using a color chart for more precise comparisons. * Extend the experiment with sodium halide salts to confirm consistency across different cations. * Use cyclohexane as an organic solvent to extract displaced halogens (especially iodine and bromine) for clearer visualization. ====Safety Precautions==== * Wear safety goggles and a lab coat at all times. * Handle chlorine, bromine, and iodine solutions with care; they can be irritants or toxic. * Perform the experiment in a well-ventilated area or fume hood. * Avoid direct contact with chemicals; use droppers and gloves. * Dispose of waste solutions properly according to school or local safety guidelines. ====Questions to Consider==== * Which halogens displaced others in the reactions? (Chlorine displaces bromide and iodide; bromine displaces iodide; iodine does not displace others.) * How does this experiment support the halogen reactivity series? (Reactivity decreases down Group 17: Cl₂ > Br₂ > I₂.) * Why might color changes be more visible in certain reactions? (Different halogens form solutions with distinctive colors, e.g., iodine brown, bromine orange.) * How does this experiment demonstrate oxidation and reduction? (The more reactive halogen is reduced to halide ions, while the less reactive halide is oxidized to elemental halogen.)