======Molar Volume of Hydrogen====== **Materials: **{{$demo.materials_description}}\\ **Difficulty: **{{$demo.difficulty_description}}\\ **Safety: **{{$demo.safety_description}}\\ \\ **Categories:** {{$demo.categories}} \\ **Alternative titles:** Magnesium and Acid Gas Collection ====Summary==== {{$demo.summary}} ====Procedure==== - Cut a short length of clean magnesium ribbon. - Fill a trough or large beaker with water and invert a gas collection tube (graduated cylinder) full of water into it. - Add dilute hydrochloric acid (or sulfuric acid) to a small flask or test tube. - Place a pre-weighed amount of magnesium ribbon into the flask, and quickly connect the flask to the gas collection tube with delivery tubing. - Allow the reaction to proceed as hydrogen gas is generated and bubbles collect in the inverted tube. - When the reaction is complete, record the volume of hydrogen collected. - Compare the measured volume with the theoretical volume calculated using the reaction equation and Avogadro’s law. ====Links==== AP Chem 3.4-Molar Volume of a Gas Lab: Tips and Calculations - Crowdedbeaker: {{youtube>kAQAYJHqdRs?}}\\ Determination of the molar Volume of a Gas at STP - North Carolina School of Science and Mathematics: {{youtube>6dmtLj2dLi0?}}\\ ====Variations==== * Compare results at different temperatures to show the effect of conditions on molar volume. ====Safety Precautions==== * Wear safety glasses and gloves. * Handle acids with care; use only dilute solutions. * Ensure apparatus is set up securely to avoid spills and breakages. * Do not ignite the collected hydrogen; keep away from open flames or sparks. * Dispose of acidic waste properly by diluting and neutralizing before disposal. ====Questions to Consider==== * What is the balanced equation for the reaction between magnesium and hydrochloric acid? (Mg + 2HCl → MgCl₂ + H₂) * How does the measured gas volume compare with the expected molar volume of a gas at room temperature and pressure (~24 dm³/mol)? * Why is it important to collect the gas over water? (It allows capture of the gas without significant loss to the air.) * What sources of error might cause the measured volume to differ from the theoretical value? (Gas loss during setup, incomplete reaction, temperature/pressure variations, or solubility of hydrogen in water.)