======Oscillating Clock Reaction====== **Materials: **{{$demo.materials_description}}\\ **Difficulty: **{{$demo.difficulty_description}}\\ **Safety: **{{$demo.safety_description}}\\ \\ **Categories:** {{$demo.categories}} \\ **Alternative titles:** Briggs-Rauscher Reaction, Color-Changing Iodine Reaction ====Summary==== {{$demo.summary}} ====Procedure==== - Prepare three separate solutions (A, B, and C) as instructed, each containing the required chemicals dissolved in distilled water. - Heat and dissolve starch in water to make a colloidal solution, then add it to solution C. - To perform the demonstration, combine equal volumes of solutions A and B in a beaker. - Immediately add the same volume of solution C to the mixture. - Observe as the solution oscillates between amber and blue-black colors every few seconds. - After several minutes, the oscillations will stop, leaving the solution dark-blue. ====Links==== The Briggs-Rauscher Iodine Oscillator - mrhomescientist: {{youtube>_gyzhvMLImg?}}\\ Recreating the Briggs-Rauscher oscillating reaction - NileRed: {{youtube>SCoLMfplVWs?}}\\ 📄 Briggs-Rauscher Reaction - ChemTalk: [[https://chemistrytalk.org/briggs-rauscher-reaction/]]\\ ====Variations==== * Scale the volumes up or down depending on the size of the audience. * Experiment with slightly different starch concentrations to vary the intensity of the blue color. * Record the oscillations with a camera and play back in time-lapse to emphasize the repeating changes. ====Safety Precautions==== * Wear safety glasses, gloves, and a lab coat when handling all chemicals. * Handle 30% hydrogen peroxide with care; it can burn skin. * Handle sulfuric acid with caution; it is highly corrosive. * Avoid inhaling iodine vapors; they are toxic and corrosive. Perform the reaction in a well-ventilated area or fume hood. * Clean spills and stains with a sodium thiosulfate solution. * Dispose of the final solution properly using sodium thiosulfate neutralization. ====Questions to Consider==== * Why does the reaction oscillate between colors rather than simply changing once? (Because some reactions proceed quickly while others are slower, causing periodic changes in the concentration of iodine species.) * What role does the starch play in the demonstration? (It forms a visible blue complex with triiodide ions, making the oscillations easier to observe.) * How does the manganese (II) ion affect the reaction? (It acts as a catalyst, producing intermediate species that help drive the oscillations.) * What eventually causes the oscillations to stop? (One or more reactants are consumed, preventing further regeneration of intermediates.)