demonstrations:boiling_cold
Boiling Cold
Materials: ★★★ Requires materials not commonly found in school laboratories
Difficulty: ★★☆ Can be done by science teachers
Safety: ★★★ Only to be attempted with adequate safety procedures and trained staff
Categories: Particles and States of Matter, Pressure and Fluids
Alternative titles: Butane Boiling, Evaporation Cooling
Summary
This demonstration uses liquid butane in a plastic bag to show evaporation and boiling under reduced pressure. As the butane evaporates, it absorbs heat, cooling the bag and causing condensation of water vapor on the outside.
Procedure
- Open a large zipper-lock plastic bag and place the nozzle of a butane spray can inside.
- Seal the bag around the nozzle.
- Spray butane into the bag for 3–5 seconds, then seal the bag fully. A small amount of liquid butane should collect inside.
- Tilt the bag to allow the liquid butane to flow from one corner to another. Observe water vapor condensing on the outside of the bag.
- Hold the corner of the bag containing the liquid and observe as it boils vigorously, inflating the bag.
Links
Boiling Cold - FlinnScientific:
📄 Boiling Cold - FlinnScientific: https://www.flinnsci.ca/api/library/Download/f9b62167e59a49c2aeabae30748d110e
Variations
- Compare how quickly condensation forms on the outside of the bag at different room humidities.
- Relate this to condensation on cold drinks or sweating pipes.
Safety Precautions
- Safety goggles, chemical-resistant gloves, and a chemical apron required.
- Butane is flammable - keep away from open flames and electrical sparks.
- Avoid direct skin contact with liquid butane, which can cause frostbite.
- Perform in a well-ventilated area.
- Dispose of butane gas safely by venting the bag in a fume hood or well-ventilated space.
Questions to Consider
- Why does liquid butane boil at room temperature when released into the bag? (Because reducing the pressure lowers its boiling point to below room temperature.)
- Why does water condense on the outside of the bag? (The butane absorbs heat as it evaporates, cooling the bag below the dew point of the surrounding air.)
- How does this experiment illustrate the cooling effect of evaporation? (Evaporation is endothermic, so it removes heat from the surroundings, making objects feel cold.)
- Where do we see similar effects in daily life? (Sweating, condensation on cold drinks, air conditioning systems.)