Copper Plating Iron
Materials: ★★☆ Available in most school laboratories or specialist stores
Difficulty: ★☆☆ Can be easily done by most teenagers
Safety: ★☆☆ Minimal safety procedures required
Categories: Elements and Periodic Table, Oxidation and Reduction
Alternative titles: Single Displacement Redox Reaction
Summary
When an iron nail is placed in a solution of copper sulfate, a single displacement reaction occurs. Iron displaces copper from the solution, forming iron(II) sulfate and depositing reddish-brown copper metal on the nail while the solution’s blue color fades.
Procedure
- Fill a small beaker with copper sulfate solution.
- Place a clean iron nail into the solution.
- Leave the nail in the solution for several minutes.
- Observe the reddish-brown copper coating forming on the nail (it probably won't be smooth, but copper will form).
- Note the gradual fading of the blue color in the solution as Cu²⁺ ions are replaced by Fe²⁺ ions.
Links
Redox Single Displacement Reaction of Copper 2 Sulfate & Iron in RamZland - RamZland:
📄 Copper Plating (Single displacement with iron/CuSO₄) - Dnnovate Ltd.: https://www.medhavatika.com/copper-plating-single-displacement-with-iron-cuso%E2%82%84/
Variations
- Use steel wool or different forms of iron instead of an iron nail.
- Compare the displacement reactions of different metals (e.g., zinc or magnesium in copper sulfate solution).
- Measure the mass of the iron nail before and after to quantify copper deposition.
Safety Precautions
- Avoid contact of copper sulfate with eyes and wash hands after the experiment.
- Dispose of the copper sulfate solution according to local regulations; do not pour down the drain.
Questions to Consider
- Why does copper coat the iron nail? (Iron is more reactive than copper and displaces it from solution.)
- What evidence shows a chemical reaction has taken place? (Deposition of copper, fading of blue solution, formation of Fe²⁺ ions.)
- How is this reaction an example of redox? (Iron undergoes oxidation to Fe²⁺, while Cu²⁺ undergoes reduction to copper metal.)
- What role does the reactivity series play in predicting whether displacement will occur? (A more reactive metal will displace a less reactive one from its compound.)