Endothermic and Exothermic Dissolving
Materials: ★★☆ Available in most school laboratories or specialist stores
Difficulty: ★☆☆ Can be easily done by most teenagers
Safety: ★★☆ Some safety precautions required to perform safely
Categories: Thermochemistry, Water and Solubility
Alternative titles: Hot and Cold Packs, Energy Changes When Substances Dissolve
Summary
This demonstration compares two reactions: one that absorbs heat from the surroundings (endothermic) and one that releases heat (exothermic). Students can observe changes in temperature and feel whether the container becomes hot or cold.
Procedure
- Put on safety goggles and gloves.
- Experiment 1 (Endothermic):
- Place a small amount of solid ammonium chloride and solid barium hydroxide in a beaker.
- Stir the mixture with a glass rod.
- Observe how the temperature drops sharply, and note that the beaker feels very cold (sometimes cold enough to freeze water underneath).
- Experiment 2 (Exothermic):
- Place a small piece of calcium carbonate (e.g., marble chip) into a beaker.
- Add dilute sulfuric acid.
- Observe the reaction: fizzing/bubbling due to carbon dioxide release, and the beaker becoming warm as heat is released.
- Compare the temperature changes in both experiments.
Links
demonstration of exothermic and endothermic reactions - Mireille Tannous:
Hot Pack vs Cold Pack - Exothermic vs Endothermic Chemical Reactions - Ed Reeves:
📄 Temperature Changes in Dissolving - ACS: https://www.acs.org/middleschoolchemistry/lessonplans/chapter5/lesson9.html
Variations
- Try other common exothermic reactions, such as dissolving calcium chloride in water.
- Try other endothermic reactions, such as dissolving potassium chloride or ammonium nitrate in water.
- Use a thermometer to measure exact temperature changes for quantitative comparison.
Safety Precautions
- Always wear safety goggles and gloves.
- Handle sulfuric acid carefully—use only dilute solutions.
- Barium hydroxide is corrosive and toxic; avoid skin contact and inhalation.
- Conduct the experiments in a well-ventilated area or under a fume hood.
- Dispose of chemical waste according to school or local regulations.
Questions to Consider
- Which reaction was exothermic and which was endothermic? (Calcium carbonate + sulfuric acid is exothermic; barium hydroxide + ammonium chloride is endothermic.)
- Why does the temperature decrease in an endothermic reaction? (The reaction absorbs energy from the surroundings, lowering the temperature.)
- Why does the temperature increase in an exothermic reaction? (The reaction releases energy to the surroundings as heat.)
- What observable evidence helps distinguish these two types of reactions? (Temperature change, container hot or cold, gas release, and other visual signs.)
- How do these energy changes connect to real-life examples like cold packs and hand warmers? (Cold packs use endothermic dissolving reactions; hand warmers use exothermic crystallization or oxidation reactions.)