demonstrations:endothermic_exothermic_dissolving

Endothermic and Exothermic Dissolving

Materials: ★★☆ Available in most school laboratories or specialist stores
Difficulty: ★☆☆ Can be easily done by most teenagers
Safety: ★★☆ Some safety precautions required to perform safely

Categories: Thermochemistry, Water and Solubility

Alternative titles: Hot and Cold Packs, Energy Changes When Substances Dissolve

Summary

This demonstration compares two reactions: one that absorbs heat from the surroundings (endothermic) and one that releases heat (exothermic). Students can observe changes in temperature and feel whether the container becomes hot or cold.

Procedure

- Put on safety goggles and gloves.

  1. Experiment 1 (Endothermic):
  2. Place a small amount of solid ammonium chloride and solid barium hydroxide in a beaker.
  3. Stir the mixture with a glass rod.
  4. Observe how the temperature drops sharply, and note that the beaker feels very cold (sometimes cold enough to freeze water underneath).
  5. Experiment 2 (Exothermic):
  6. Place a small piece of calcium carbonate (e.g., marble chip) into a beaker.
  7. Add dilute sulfuric acid.
  8. Observe the reaction: fizzing/bubbling due to carbon dioxide release, and the beaker becoming warm as heat is released.
  9. Compare the temperature changes in both experiments.

demonstration of exothermic and endothermic reactions - Mireille Tannous:


Hot Pack vs Cold Pack - Exothermic vs Endothermic Chemical Reactions - Ed Reeves:


📄 Temperature Changes in Dissolving - ACS: https://www.acs.org/middleschoolchemistry/lessonplans/chapter5/lesson9.html

Variations

  • Try other common exothermic reactions, such as dissolving calcium chloride in water.
  • Try other endothermic reactions, such as dissolving potassium chloride or ammonium nitrate in water.
  • Use a thermometer to measure exact temperature changes for quantitative comparison.

Safety Precautions

  • Always wear safety goggles and gloves.
  • Handle sulfuric acid carefully—use only dilute solutions.
  • Barium hydroxide is corrosive and toxic; avoid skin contact and inhalation.
  • Conduct the experiments in a well-ventilated area or under a fume hood.
  • Dispose of chemical waste according to school or local regulations.

Questions to Consider

  • Which reaction was exothermic and which was endothermic? (Calcium carbonate + sulfuric acid is exothermic; barium hydroxide + ammonium chloride is endothermic.)
  • Why does the temperature decrease in an endothermic reaction? (The reaction absorbs energy from the surroundings, lowering the temperature.)
  • Why does the temperature increase in an exothermic reaction? (The reaction releases energy to the surroundings as heat.)
  • What observable evidence helps distinguish these two types of reactions? (Temperature change, container hot or cold, gas release, and other visual signs.)
  • How do these energy changes connect to real-life examples like cold packs and hand warmers? (Cold packs use endothermic dissolving reactions; hand warmers use exothermic crystallization or oxidation reactions.)