demonstrations:growing_bismuth_crystals

Growing Bismuth Crystals

Materials: ★★★ Requires materials not commonly found in school laboratories
Difficulty: ★★★ Requires a more experienced teacher
Safety: ★★☆ Some safety precautions required to perform safely

Categories: Crystals, Elements and Periodic Table

Alternative titles:

Summary

Bismuth metal is melted and carefully cooled to form colorful, geometric crystals.

Procedure

  1. Melt solid bismuth in a heat-safe container, such as a crucible. (A campfire, camp stove, or burner can be used for heating.)
  2. Skim impurities from the molten bismuth and keep it in an insulated crucible to cool slowly.
  3. After about 45–60 minutes, pour out the remaining liquid bismuth, leaving crystals attached to the inner surface of the crucible.
  4. Use a blowtorch and hammer to remove the crystals from the crucible.
  5. Cut crystals apart to isolate distinct hopper formations, recovering leftover bismuth for reuse.

How to Make Bismuth Crystals - NightHawkInLight:


Growing Bismuth Crystals - Cedar Rapids Public Library:


📄 Growing Bismuth Crystals - Chem Talk: https://chemistrytalk.org/hobbies-bismuth-crystals/

Variations

  • Try the “single crystal” method: allow crystals to form on the surface of an open pot of molten bismuth, then pluck them out.
  • Adjust cooling rate—slower cooling produces larger crystals, while faster cooling leads to smaller ones.
  • Experiment with different crucible shapes and sizes to influence crystal formation.

Safety Precautions

  • Safety goggles required.
  • Wear forge gloves when handling hot crucibles and molten metal.
  • Keep a fire extinguisher nearby.
  • Do not attempt to melt bismuth on an electric hotplate—it does not get hot enough.
  • Handle crystals carefully when cutting; bismuth is brittle and can fracture easily.

Questions to Consider

  • Why does bismuth form hopper-shaped crystals instead of flat ones? (Because the edges of the crystal grow faster than the center, leaving hollow steps.)
  • How does the cooling rate affect the size of the crystals? (Slower cooling allows atoms to arrange into larger, more ordered structures.)
  • Why is insulation helpful for growing larger crystals? (It keeps heat in, allowing for a slower and more controlled cooling process.)
  • What makes bismuth different from many other metals in terms of appearance? (It forms iridescent oxide layers that create rainbow-like colors on the surface.)