demonstrations:growing_bismuth_crystals
Growing Bismuth Crystals
Materials: ★★★ Requires materials not commonly found in school laboratories
Difficulty: ★★★ Requires a more experienced teacher
Safety: ★★☆ Some safety precautions required to perform safely
Categories: Crystals, Elements and Periodic Table
Alternative titles:
Summary
Bismuth metal is melted and carefully cooled to form colorful, geometric crystals.
Procedure
- Melt solid bismuth in a heat-safe container, such as a crucible. (A campfire, camp stove, or burner can be used for heating.)
- Skim impurities from the molten bismuth and keep it in an insulated crucible to cool slowly.
- After about 45–60 minutes, pour out the remaining liquid bismuth, leaving crystals attached to the inner surface of the crucible.
- Use a blowtorch and hammer to remove the crystals from the crucible.
- Cut crystals apart to isolate distinct hopper formations, recovering leftover bismuth for reuse.
Links
How to Make Bismuth Crystals - NightHawkInLight:
Growing Bismuth Crystals - Cedar Rapids Public Library:
📄 Growing Bismuth Crystals - Chem Talk: https://chemistrytalk.org/hobbies-bismuth-crystals/
Variations
- Try the “single crystal” method: allow crystals to form on the surface of an open pot of molten bismuth, then pluck them out.
- Adjust cooling rate—slower cooling produces larger crystals, while faster cooling leads to smaller ones.
- Experiment with different crucible shapes and sizes to influence crystal formation.
Safety Precautions
- Safety goggles required.
- Wear forge gloves when handling hot crucibles and molten metal.
- Keep a fire extinguisher nearby.
- Do not attempt to melt bismuth on an electric hotplate—it does not get hot enough.
- Handle crystals carefully when cutting; bismuth is brittle and can fracture easily.
Questions to Consider
- Why does bismuth form hopper-shaped crystals instead of flat ones? (Because the edges of the crystal grow faster than the center, leaving hollow steps.)
- How does the cooling rate affect the size of the crystals? (Slower cooling allows atoms to arrange into larger, more ordered structures.)
- Why is insulation helpful for growing larger crystals? (It keeps heat in, allowing for a slower and more controlled cooling process.)
- What makes bismuth different from many other metals in terms of appearance? (It forms iridescent oxide layers that create rainbow-like colors on the surface.)