Iodine Vapor Fingerprints
Materials: ★★☆ Available in most school laboratories or specialist stores
Difficulty: ★★☆ Can be done by science teachers
Safety: ★★☆ Some safety precautions required to perform safely
Categories: Forensics
Alternative titles: Revealing Fingerprints with Iodine Fuming
Summary
This demonstration shows how iodine vapor can reveal fingerprints by binding to the fatty residues left behind on surfaces.
Procedure
- Place a sheet of paper with a fingerprint inside a sealable container such as a jar or plastic box.
- Add a few solid iodine crystals to the bottom of the container (do not let them touch the paper).
- Seal the container and wait a few minutes for iodine vapors to fill the space.
- Observe the fingerprint as it gradually appears brown where iodine binds to the oils.
- Remove the paper when the fingerprint is clear.
Links
The Home Scientist 006 - Forensic Fingerprinting I: Iodine Fuming:
Fingerprint Fixing with Iodine - RACInational:
📄 Iodine fingerprint - MEL Science (uses copper sulfate and potassium iodide instead of solid iodine): https://melscience.com/AU-en/chemistry/experiments/diffusion-iodine-fingers/?srsltid=AfmBOopdRexxLJsB66vaYzwTo4NRhco_DSCZ05F8UynAJFxTpqRPYMWn
Variations
- Try developing fingerprints on different porous surfaces such as cardboard or fabric.
- Place the container on a warm (not hot) surface to increase sublimation and speed up fingerprint development.
- Use starch solution after iodine development; the starch-iodine complex produces a dark blue color, making the fingerprint more visible.
Safety Precautions
- Wear safety goggles and protective gloves.
- Handle iodine crystals with care; avoid direct skin contact.
- Perform the experiment in a well-ventilated area or under a fume hood to avoid inhaling vapors.
- Keep iodine crystals sealed when not in use, as vapors can irritate eyes and lungs.
- Dispose of iodine residues safely according to local chemical disposal rules.
Questions to Consider
- Why does iodine make the fingerprint visible? (Because iodine vapors bind to fats and oils present in fingerprints.)
- Why does heating the iodine speed up the fingerprint appearance? (Heating increases sublimation, releasing vapors faster.)
- Why do the fingerprints fade over time? (Iodine sublimes back into the air, leaving less bound to the fingerprint.)
- What is the advantage of using iodine fuming over ink or powder methods? (It works well on porous surfaces like paper where powders are less effective.)